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Effects of system-bath coupling on Photosynthetic heat engine: A polaron master equation approach

机译:系统 - 浴耦合对光合热力发动机的影响:极化子   主方程方法

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摘要

In this paper, we apply the polaron master equation, which offers thepossibilities to interpolate between weak and strong system-bath coupling, tostudy how system-bath couplings affect charge transfer processes in PhotosystemII reaction center (PSII RC) inspired quantum heat engine (QHE) model in a wideparameter range. The effects of bath correlation and temperature, together withthe combined effects of these factors are also discussed in details. Theresults show a variety of dynamical behaviours. We interpret these results interms of noise-assisted transport effect and dynamical localization whichcorrespond to two mechanisms underpinning the transfer process inphotosynthetic complexes: One is resonance energy transfer and the other isdynamical localization effect captured by the polaron master equation. Theeffects of system-bath coupling and bath correlation are incorporated in theeffective system-bath coupling strength determining whether noise-assistedtransport effect or dynamical localization dominates the dynamics andtemperature modulates the balance of the two mechanisms. Furthermore, these twomechanisms can be attributed to one physical origin: bath-induced fluctuations.The two mechanisms is manifestations of dual role played by bath-inducedfluctuations within respective parameter range. In addition, we find that theeffec- tive voltage of QHE exhibits superior robustness with respect to thebath noise as long as the system-coupling strength is not too large.
机译:在本文中,我们使用了极化子主方程,该方程可在弱和强系统浴耦合之间进行插值,研究系统浴耦合如何影响光系统II反应中心(PSII RC)激发的量子热机(QHE)中的电荷转移过程。宽参数范围内的模型。还详细讨论了熔池相关性和温度的影响,以及这些因素的综合影响。结果显示出各种动态行为。我们用噪声辅助传输效应和动态定位来解释这些结果,这与支撑光合配合物传递过程的两种机制相对应:一种是共振能量传递,另一种是通过极化子主方程捕获的动态定位效应。系统-浴耦合和浴相关的效果被合并到有效的系统-浴耦合强度中,从而确定噪声辅助的运输效应或动力局部化主导着动力学,而温度调节着这两种机制之间的平衡。此外,这两种机制可以归因于一个物理起源:浴引起的波动。这两种机制是浴引起的波动在相应参数范围内发挥双重作用的表现。此外,我们发现,只要系统耦合强度不太大,QHE的有效电压就对浴缸噪声表现出优异的鲁棒性。

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